| Disc: 1 |
| 1. | Aquarius [From Hair] - Steve Brooker, NSO Ensemble, , Caroline O'Connor |
| 2. | If I Can't Love Her [From Beauty and the Beast] - Ethan Freeman, National Symphony Orchestra, Martin Yates |
| 3. | I Could Have Danced All Night [From My Fair Lady] - Katrina Murphy, National Symphony Orchestra |
| 4. | Can You Feel the Love Tonight? [From The Lion King] - John Barrowman, National Symphony Orchestra, Martin Yates |
| 5. | What I Did for Love [from a Chorus Line] - National Symphony Orchestra, Catherine Porter, Martin Yates |
| 6. | This Is the Moment [From Jekyll and Hyde] - Gary Mauer, National Symphony Orchestra, Martin Yates |
| 7. | All That Jazz [From Chicago] - Paulette Ivory, Julian Kelly, Katrina Murphy, National Symphony Orchestra, Sally Ann Triplett |
| 8. | Impossible Dream [From Man of La Mancha] - Ethan Freeman, National Symphony Orchestra, Martin Yates |
| 9. | America [From West Side Story] - National Symphony Orchestra |
| 10. | Written in the Stars [From Aida] - Simon Bowman, NSO Ensemble, Sally Ann Triplett, Martin Yates |
| 11. | Mame [From Mame] - Jerry Lanning, National Symphony Orchestra, Martin Yates |
| 12. | Some Enchanted Evening [From South Pacific] - Thomas Allen, John Owen Edwards, Philharmonic Orchestra |
| 13. | I Am What I Am [From LA Cage aux Follies] - Janet Glazener, Leslie Uggams |
| 14. | One Song Glory [From Rent] - Sean McDermott, Martin Yates |
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| Disc: 2 |
| 1. | Phantom of the Opera [From The Phantom of the Opera] - Ethan Freeman, Claire Moore, National Symphony Orchestra, Martin Yates |
| 2. | I Dreamed a Dream [From Les Miserables] - National Symphony Orchestra, Jacqui Scott, Martin Yates |
| 3. | Bui Doi [From Miss Saigon] - Ethan Freeman, National Symphony Orchestra, Martin Yates |
| 4. | As Long as He Needs Me [From Oliver!] - John Owen Edwards, National Symphony Orchestra, |
| 5. | Time Warp [From the Rocky Horror Picture Show] - Aidan Bell, Anita Dobson, NSO Ensemble, Martin Yates, |
| 6. | Memory [From Cats] - Kim Criswell, National Symphony Orchestra, Martin Yates |
| 7. | Why God Why [From Miss Saigon] - Graham Bickley, National Symphony Orchestra, Martin Yates |
| 8. | I Know Him So Well [From Chess] - Katrina Murphy, NSO Ensemble, Sally Ann Triplett, Martin Yates |
| 9. | One Day More [From Les Miserables] - National Symphony Orchestra, Martin Yates |
| 10. | Peggy Sue [From Buddy Holly Story] - Dominic Curtis |
| 11. | Empty Charis at Empty Tables [From Les Miserables] - Graham Bickley, National Symphony Orchestra, Martin Yates |
| 12. | Dancing Queen [From Mamma Mia!] - Julian Kelly, NSO Ensemble, , Caroline O'Connor |
| 13. | All I Ask of You [From The Phantom of the Opera] - Andrew Halliday, Katrina Murphy, National Symphony Orchestra, Martin Yates |
| 14. | We Will Rock You [From We Will Rock You] - Martin Yates |
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| Disc: 3 |
| 1. | It's a Grand Night for Singing [From State Fair] - National Symphony Orchestra |
| 2. | If I Were a Rich Man [From Fiddler on the Roof] - John Owen Edwards, Jerry Lanning, National Symphony Orchestra |
| 3. | I Talk to the Trees [From Paint Your Wagon] - Ethan Freeman, National Symphony Orchestra, Martin Yates |
| 4. | Over the Rainbow [From The Wizard of Oz] - Gillian Bevan, , John Owen Edwards, , Royal Shakespeare Company |
| 5. | Bless Yore Beautiful Hide [From Seven Brides for Seven Brothers] - Hal Fowler, National Symphony Orchestra, Martin Yates |
| 6. | Grease [From Grease] - John Barrowman, NSO Ensemble, Martin Yates |
| 7. | Woman in Love [From Guys and Dolls] - Gregg Edelman, John Owen Edwards, Emily Loesser, National Symphony Orchestra |
| 8. | Secret Love [From Calamity Jane] - Debbie Gravitte, National Symphony Orchestra |
| 9. | Quintet [From West Side Story] - National Symphony Orchestra |
| 10. | I Will Always Love You [From the Best Little Whorehouse in Texas] - Salena Jones, John Pearce |
| 11. | Money, Money [From "Caberet"] - Maria Friedman, National Symphony Orchestra, Jonathan Pryce |
| 12. | If My Friends Could See Me Now (Sweet Charity) - Jacqueline Dankworth, National Symphony Orchestra, Martin Yates |
| 13. | Thank Heaven for Little Girls [From Gigi] - Ron Moody, National Symphony Orchestra, Martin Yates |
| 14. | Singin' in the Rain [From Singin' in the Rain] - Craig Barna, National Symphony Orchestra, Paul Robinson |
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